Earlier Yifan won against other higher rated players, Judit Polgar and Le Quang Liem.
Despite being black, Yifan bravely entered one of the sharpest openings known - Sicilian Naidorf Poisoned Pawn. Shirov is renowned for his tactical skills as well as the perfect endgame technique.
But Yifan first neutralised white's initiative, and then outplayed Shirov in a tricky Rook endgame.
Yifan is now entering the final round as sole leader in the tournament. Follow the live games with computer analysis from 11:00 CET Thursday.
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